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Arab Journal of Nuclear Sciences and Applications
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Journal Archive
Volume Volume 54 (2021)
Issue Issue 1
Volume Volume 53 (2020)
Volume Volume 52 (2019)
Volume Volume 51 (2018)
Alfayyadh, A., Khalil, M., Basfar, A., Lotfy, S. (2021). Synthesis and Characterization of Poly (vinyl alcohol) / Fullerene C60 Membrane via Chemical and Radiation Crosslinking. Arab Journal of Nuclear Sciences and Applications, 54(1), 28-39. doi: 10.21608/ajnsa.2020.33101.1368
Aamer Alfayyadh; Mutasim I. Khalil; Ahmed Basfar; Salah Lotfy. "Synthesis and Characterization of Poly (vinyl alcohol) / Fullerene C60 Membrane via Chemical and Radiation Crosslinking". Arab Journal of Nuclear Sciences and Applications, 54, 1, 2021, 28-39. doi: 10.21608/ajnsa.2020.33101.1368
Alfayyadh, A., Khalil, M., Basfar, A., Lotfy, S. (2021). 'Synthesis and Characterization of Poly (vinyl alcohol) / Fullerene C60 Membrane via Chemical and Radiation Crosslinking', Arab Journal of Nuclear Sciences and Applications, 54(1), pp. 28-39. doi: 10.21608/ajnsa.2020.33101.1368
Alfayyadh, A., Khalil, M., Basfar, A., Lotfy, S. Synthesis and Characterization of Poly (vinyl alcohol) / Fullerene C60 Membrane via Chemical and Radiation Crosslinking. Arab Journal of Nuclear Sciences and Applications, 2021; 54(1): 28-39. doi: 10.21608/ajnsa.2020.33101.1368

Synthesis and Characterization of Poly (vinyl alcohol) / Fullerene C60 Membrane via Chemical and Radiation Crosslinking

Article 3, Volume 54, Issue 1, Winter 2021, Page 28-39  XML PDF (1.58 MB)
Document Type: Original Article
DOI: 10.21608/ajnsa.2020.33101.1368
Authors
Aamer Alfayyadh1; Mutasim I. Khalil2; Ahmed Basfar1; Salah Lotfy email orcid 3
1Radiation Technology Center, Nuclear Science Research Institute, King Abdulaziz City for Science and Technology (KACST), P. O. Box 6086, Riyadh 11442, Saudi Arabia
2Department of Chemistry, Faculty of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
3Polymer Chemistry Department, National Center for Radiation Research and Technology, Egyptian Atomic Energy Authority
Abstract
Abstract
Fullerene C60 (FULL-C60) was used as a nano-filler in the preparation of the chemical-crosslinking polyvinyl alcohol (PVA) by glutaraldehyde (Glut) which, copolymerized with acrylate oligomers, 2-carboxyethyl acrylate (CEA) followed by gamma irradiation. The effect of the FULL-C60 content on the gel content and swelling behavior of Glut-(PVA/CEA)-FULL-C60 copolymer hydrogel was investigated. The results revealed an increase in the gel content and a significant reduction in swelling of the nanocomposite material. There are influences for the PVA molecular weight, fullerene content, and absorbed dose on the gel content of the prepared nanocomposite. The irradiation of chemical crosslinked nanocomposites demonstrated approximately a 90% gelation over a range of 50-300 kGy irradiation doses. A scanning electron microscopy (SEM) analysis showed a homogeneous distribution of nanocomposites in the composite matrix. Improvement in the thermal stability of radiation Glut-(PVA/CEA) and Glut-(PVA-CEA)-FULL-C60 was evaluated using thermogravimetric analysis (TGA). The mechanical properties were examined via dynamic mechanical analysis (DMA) which showed significant variation because of the addition of nanocomposites and irradiation doses.
Keywords
Radiation; Poly(vinyl alcohol); Nanocomposite materials; Fullerene C60
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